Colloidal Synthesis of Hollow Cobalt Sulfide Nanocrystals

Formation of cobalt sulfide hollow nanocrystals through a mechanism similar to the Kirkendall Effect has been investigated in detail. It is found that performing the reaction at > 120 °C leads to fast formation of a single void inside each shell, whereas at room temperature multiple voids are formed within each shell, which can be attributed to strongly temperature‐dependent diffusivities for vacancies. The void formation process is dominated by outward diffusion of cobalt cations; still, the occurrence of significant inward transport of sulfur anions can be inferred as the final voids are smaller in diameter than the original cobalt nanocrystals. Comparison of volume distributions for initial and final nanostructures indicates excess apparent volume in shells, implying significant porosity and/or a defective structure. Indirect evidence for fracture of shells during growth at lower temperatures was observed in shell‐size statistics and transmission electron microscopy images of as‐grown shells. An idealized model of the diffusional process imposes two minimal requirements on material parameters for shell growth to be obtainable within a specific synthetic system.     

Encapsulation and Ostwald Ripening of Au and Au–Cl Complex Nanostructures in Silica Shells

We report a general template strategy for rational fabrication of a new class of nanostructured materials consisting of multicore shell particles. Our approach is demonstrated by encapsulating Au or Pt nanoparticles in silica shells. Other superstructures of these hollow shells, like dimers, trimers, and tetramers can also be formed by nanoparticle‐mediated self‐assembly. We have also used the as‐prepared multicore Au–silica hollow particles to perform the first studies of Ostwald ripening in confined microspace, in which chloride was found to be an efficient mediating ligand. After treatment with aqua regia, Au–Cl complex is formed inside the shell, and is found to be very active under in situ transmission electron microscopy observations while confined in a microcell. This aspect of the work is expected to motivate further in situ studies of confined crystal growth.     

川东北飞仙关组碳酸盐岩气藏产能影响因素及压裂酸化新技术探讨

川东北地区飞仙关组碳酸盐岩气藏的储集层条件起好，不论直井还是水平井均可获高产工业气流，投产前的解堵酸化均可实现大幅度增产。在分析介绍该地区气藏地质特征的基础上，全面剖析了影响产能的主要因素，并对多功能深部酸化技术方案和稠化酸加砂压裂技术方案进行了具体探讨。     

高温旋风除尘器的设计

在PTA(精对苯二甲酸)的生产过程中,工艺废气经尾气膨胀透平机降压后进入RTO蓄热式焚烧炉将有毒有害的有机物焚烧分解后排入大气,为了达到粉尘的排放标准(小于120mg/m~3),在焚烧炉之后加上这台高温烟气除尘器,废气经除尘后达到了排放标准,而且最大程度地减少了热量损失,实践证明此项改造是成功的。文章探讨如何进行高温烟气除尘器的设计,并介绍了高温多管陶瓷旋风烟气除尘器的结构。     

从数据库到数据仓库——广电未来的制胜武器

在目前数据爆炸、信息匮乏的情况下，需要利用数据仓库系统集成1个或多个独立传统数据库数据，通过分析海量数据发现市场潜在规律，获取商业信息以支持商业决策，这将是广电未来的制胜武器。     

低阻VDMOSFET的优化设计与制造

文章对9926型双N沟增强型VDMOSFET进行了结构和版图的优化设计。给出了该器件的纵横向结构参数,材料的物理参数和版图总体结构。单胞结构的优化设计使单胞密度达到204万个/cm2,比国际市场现有产品的单胞密度(156万个/cm2)提高了30%。这种设计采用浅n+注入工艺可使器件生产成本下降31%。最后对研制结果进行了分析讨论。     

3-N-丙酰基-2-芳基-5-(3-碘苯基)-1,3,4-(噁)唑啉类化合物的合成及表征

以3-碘苯甲酸为原料，在浓硫酸作用下与乙醇反应制得3-碘苯甲酸乙酯（1），再以无水乙醇为溶剂，在105℃化合物1与80％的水合肼反应8h，制得3-碘苯甲酰肼（2）。在无水乙醇中，在90～95℃化合物2分别与4-甲基苯甲醛、2-氯苯甲醛、4-氯苯甲醛、4-羟基苯甲醛、2，4-二氯苯甲醛、4-甲氧基苯甲醛、3-硝基苯甲醛、4-硝基苯甲醛和4-二甲氨基苯甲醛反应得到相应的酰腙E3（a～i）]。最后化合物3（a～i）分别与丙酸酐脱水环化成了3-M丙酰基-2-芳基-5-（3-碘苯基）-1，3，4-噁唑啉类化合物E4（a～i）]，收率分别为86．2％，70．5％，80．1％，68．2％，62．4％，75．2％，73．2％，70．5％和63．2％。并通过元素分析，IR，^1H NMR和MS对化合物4（a～i）的结构进行了表征。     

欢2-平1水平井钻井技术

欢2-平1井是辽河油田第一口稀油水平井探井，油藏类型为层状边水油藏，施工过程中克服了钻经地层松散、成岩性较差、水平段中靶精度要求高、地层易漏失等技术难题。文中对欢2-平1井的工程设计、轨迹控制技术、钻井液技术、完井技术进行了介绍，施工中对出现的漏失采取了适宜的解决措施，给出了实施稀油水平井的认识和体会。     

加氢反应器制造技术的新进展

随着加氢装置的大型化,对加氢反应器的设计、主体材质的选用及制造均提出了新的、更高的要求。文章较全面地介绍了国内外加氢反应器的设计准则、主体材质(抗氢钢)和制造技术等方面的新进展。